Diiodido[4′-(4-pyridyl)-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′]copper(II)
نویسندگان
چکیده
منابع مشابه
Dimethyl(4′-pyridyl-2,2′:6′,2′′-terpyridine-κ3 N 1,N 1′,N 1′′)bis(thiocyanato-κN)tin(IV)
The Sn atom in the title compound, [Sn(CH(3))(2)(NCS)(2)(C(20)H(14)N(4))], is N,N',N''-chelated by the terpyridine part of the N-heterocycle. The Sn atom exists in a trans-C(2)SnN(5) penta-gonal-bipyramidal geometry [C-Sn-C = 173.66 (8)°] with the methyl groups in axial and the N atoms in equatorial positions.
متن کاملDiethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phenyl]phosphonate
The title compound, C25H24N3O3P, was obtained by catalytic phospho-nation of 4'-(4-bromphen-yl)-2,2':6',2''-terpyridine. The terpyridine moiety is nearly planar, the dihedral angles between the central and the outer rings being 4.06 (9) and 5.39 (9)°. The N atoms in the two pyridine rings are oriented nearly anti-periplanar to that of the central ring. The benzene ring is rotated out of the pla...
متن کامل4′-[4-(Pyridin-2-yl)phenyl]-2,2′:6′,2′′-terpyridine
In the title compound, C(26)H(18)N(4), each ring is almost planar with maximum deviation of 0.012 (5) Å. In the crystal, mol-ecules are stacked by weak C-H⋯π inter-actions, forming a three-dimensional framework.
متن کامل[4′-(4-Aminophenyl)-2,2′:6′,2′′-terpyridine]chloridopalladium(II) chloride
The Pd(II) atom in the complex cation of the title compound, [PdCl(C(21)H(16)N(4))]Cl, is coordinated by three N atoms derived from the terpyridine ligand and a chloride ion, which define a distorted PdClN(3) square-planar coordination geometry. In the crystal, the presence of N-H⋯Cl hydrogen bonds involving the amino H atom and chloride anions link two cations and two anions into a four-ion ag...
متن کاملSynthesis of aryl-substituted 2-pyridyl-1,10-phenanthrolines; a series of oriented terpyridine analogues.
A 3 x 3 matrix of manisyl (4-methoxy-2,6-dimethylphenyl) substituted pyridyl-1,10-phenanthrolines has been synthesized by utilizing a general palladium catalyzed cross-coupling procedure. The directionality of these terdentate ligands will generate chiral octahedral ML(2) complexes, potentially useful for the metal templated synthesis of topologically chiral structures.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810020635